I tell him to stop, and that if he’s gonna do that, to go do it elsewhere. Anyway, he starts getting into it more and more, and his hand kinda slides to down below. I wasn’t in that kind of mood and I am naive by nature, and I was stoned, so I was pointing out how odd it was for their to be a storyline and how the camera work was professional. Eventually, we put on a video from the porn star I watched. I don’t know how we got there, I was high and drunk. ![]() Anyway we eventually got into a discussion about porn. I bought it, because hey, that’s what friends do. There were a lot of personal questions he was asking, mostly about my sex life and things regarding self esteem. Last night I met up with him and some people at a bar, all was cool, we ended up going back to his place and hanging out. I wasn’t sure what happened, but I enjoyed this person and as I said, looked up to him, so i ignored that warning sign. He’s in his early 30’s, and I’m in my mid 20’s.Ī friend of mine was very good friends with him before, but they had some kind of falling out and no longer speak. I envisioned us growing into our industry together, helping one another and so forth. Post: 30624 ⬆️ | I laced my braid with thumbtacks as a self defense tacticĪnonymous for obvious reasons, but I have this friend I look up to in terms of his professional career and the progress he’s made. **The moderators of this subreddit will set aside their opinions while moderating We want to make a place where anybody can get things off their chest without any sort of limitations. This sub was made to fulfill the original purpose of /r/offmychest. If you need a pick me up also look at these subreddits: This is a place for those that need support. All posts, besides blatant trolls or excessive circlejerking, are allowed and we will not take them down. If you are in need of one, the original /r/offmychest maintains one (Mostly for common safe spaces such as LGBT, Domestic Abuse, Sexual Abuse). This subreddit is not considered a safe space for any particular group. We also heavily encourage our users to follow the reddiquette Other Information This is a bannable offensive with zero tolerance. ![]() Do not offer money, give money, or request money.If you want to talk about something, it either has to be directly related to you or directly impacting you - no soapboxing or hot takes/unpopular opinions. ![]() If your post isn't personal in nature or in "off my chest" style, it will be removed.Posts must be personal and in "off my chest" style Pinging someone in order to harass them is a bannable offenseħ. This includes referencing another user's reddit history.ĭo not ping users who are not already in the thread. Consider creating a new reddit account just for your post.ĭo not attempt a witch hunt. Do not disclose personal information about yourself or othersĭo not reveal personally identifiable information. Please engage the community in good faith and do not test the limits of the mod teamĦ. Comments should be well-thought out and reasonable and have the goal of productive conversation with others, even if there is a disagreement Off-topic comments are rude and will be removed.Ĭalm debates are fine, name-calling and arguing is not. Egregiously breaking this rule may result in a ban. ![]()
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![]() Southwest cancellations bring four strangers together. “Many of the refunds will be handled on a case-by-case basis and teams are already engaged in those efforts,” said Dan Landson, Southwest’s public relations advisor.Ĭalifornia Southwest canceled their flights. In an email, a Southwest spokesperson said that the company launched a new online portal for customers to rebook their flights or request a refund. Many are hopeful they will be compensated for additional expenses they were forced to make amid the chaos such as renting a car or booking with another airline.Īlthough some have reported getting refunds for their canceled flights, many are still struggling to get a response. Southwest Airlines canceled more than 2,800 flights Monday, prompting an apology from the carrier’s chief executive.īeyond the logistics of getting planes back in the air and luggage back to travelers, Southwest’s customer service reputation is on the line.įrustrated fliers shared experiences across social media about waiting in long queues or on hold for hours with customer service agents, often getting disconnected before receiving any help, as they attempted to rebook or receive a refund for their travels. ![]() “The tools we use to recover from disruption serve us well 99% of the time, but clearly, we need to double down on our already existing plans to upgrade systems for these extreme circumstances so that we never again face what’s happening right now,” he said, adding that he remained optimistic that the airline will be back on track before next week.Ĭalifornia Mass Southwest Airlines cancellations strand travelers, cause chaos at airports Southwest Chief Executive Bob Jordan apologized to customers in a video posted on Twitter on Tuesday evening and said the carrier was “focused on safely getting all of the pieces back into position to end this rolling struggle.”īut those pieces - including aircraft and flight crews - were unaccounted for in dozens of locations, Jordan said, and despite the airline’s best efforts, the company needs to “significantly reduce our flying” to one-third of its schedule over the next couple of days to recoup. At LAX, the cancellations and delays create misery. ![]() California Photos: Southwest Airlines meltdown worsens California airports hit hard with mass cancellationsĪirlines cancel more than 2,800 flights Tuesday morning, the majority of them with Southwest. ![]() ![]() * Play as Star Wars: Episode II's Jango Fett in an original story line ![]() Other items available during the game include three limited-use weapons, including a heavy gun, grenade launcher, and a blaster rifle, two power-ups in the form of temporary invulnerability and longer flight time, and various pickups to replenish health and ammunition. These feathers unlock such features as outtakes and concept art. In addition to claiming bounties and completing objectives, bonuses are available by finding hidden feather icons. Players can only save their progress after each level, although the stages offer a number of checkpoints to continue from. Players must keep an eye on fuel consumption, however, as the jetpack will quickly lose power the longer the thrusters are engaged.Īs Fett delves deeper into the worlds, context sensitive areas allow him to activate switches and doors, take control of stationary turrets, and use a cutting laser to reveal new areas. Analog control means the bounty hunter can sneak, walk, or run while on the ground, and he is always free to use his jetpack's thrusters to climb into the air. Jango Fett can roll, somersault, climb hand over hand across ledges, crouch, jump, and lock onto enemies using an auto targeting system. Once a bounty has been discovered, an icon will appear on the screen to help guide players toward their target. To determine which individuals have prices on their heads, players make use of Fett's ID scanner, which will display critical information on each selected character. To help in his pursuit, Jango Fett can use his trademark dual blasters, a flamethrower, thermal grenades, toxic darts, a sniper rifle, whipcord, and two types of jetpack-mounted missiles.Īs Jango Fett travels across the 3D locales, which include the familiar worlds of Tattooine and Coruscant, he will encounter many different creatures and species. Each level features primary and secondary objectives, the majority of which involve tracking down various thugs and capturing them dead or alive. Played from a third-person perspective, the game features a total of 18 levels spread across six chapters. Boba Fett's father wears similar armor as his bounty hunter son, which means he can fly short distances with the use of a jetpack. Continued abuse of our services will cause your IP address to be blocked indefinitely.Taking place within the time period between Star Wars: Episode I and Episode II, Bounty Hunter chronicles the story of the ruthless Jango Fett as he journeys through the underbelly of the Star Wars universe to hunt down a rogue Dark Jedi. Please fill out the CAPTCHA below and then click the button to indicate that you agree to these terms. ![]() If you wish to be unblocked, you must agree that you will take immediate steps to rectify this issue. If you do not understand what is causing this behavior, please contact us here. If you promise to stop (by clicking the Agree button below), we'll unblock your connection for now, but we will immediately re-block it if we detect additional bad behavior. Overusing our search engine with a very large number of searches in a very short amount of time.Using a badly configured (or badly written) browser add-on for blocking content.Running a "scraper" or "downloader" program that either does not identify itself or uses fake headers to elude detection.Using a script or add-on that scans GameFAQs for box and screen images (such as an emulator front-end), while overloading our search engine.There is no official GameFAQs app, and we do not support nor have any contact with the makers of these unofficial apps. Continued use of these apps may cause your IP to be blocked indefinitely. This triggers our anti-spambot measures, which are designed to stop automated systems from flooding the site with traffic. 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The latest version of the Opera browser sends multiple invalid requests to our servers for every page you visit.The most common causes of this issue are: Your IP address has been temporarily blocked due to a large number of HTTP requests. ![]() You see a person’s true colors when you are no longer beneficial to their life.” Sometimes I believe in as many as six impossible things before breakfast” ![]() If you want something you never had you have to do something you’ve never done” Smile to the world and the world smiles back at you” ![]() Even if you miss, you’ll land among the stars.” One day you’ll look back and realise that you worried too much about things that don’t really matter.” Be a good person, but don’t waste time to prove it.” A real woman is her man’s personal porn star” Believe you can and you’re halfway there” You will be exactly as happy as you decide.” Actions prove who someone is, words just prove who they want to be.” ![]() I’m tired it’s too cold it’s too not it’s raining it’s too late let’s go” Good morning struggle is just another word for growth.” if you don’t step forward, you’re always in the same place.” if you don’t ask, the answer is always no. If you don’t go after what you want, you’ll never have it. With the new day comes new strength and new thoughts” Live more worry less” Short Inspirational Quotes Don’t judge someone just because they sin differently than you.” Your worst enemy cannot harm you as much as your own unguarded thoughts.” But, I promise you, when you reach your goal, it’s worth it.” You will need to push your body to its max. Favor will locate you, no matter where you are now. Not all storms come to disrupt your life, some come to clear your path.” So you have to trust that the dots will somehow connect in your future. You can’t connect the dots looking forward you can only connect them looking backwards. As long as I wake up today “you can’t take my yourth away”” You can’t control the wind but you can adjust the sails” Forget the past, but remember the lesson.” The best time to plant a tree was 20 years ago. Someone who will dance with me, kiss me when I least expect it and make me laugh. I just want a weirdo to go on adventures with. When you need something to believe in, start with yourself.” Don’t tell me sky’s the limit when there’s footprints on the moon.” She believed she could so she did” Inspirational Words & Life Quotes It’s a brand new opportunity to rebuild what you truly want.” Always remember you are braver than you believe stronger than you seem & smarter than you think” Be good enough to forgive someone, but don’t be stupid enough to trust them again.” If you want to go far, pay attention to who you are making yourself to be, in your own mind. Your vision, beliefs, values and attitudes become you through your habits and actions. This is true of buildings, cars and also human beings. Everything is created twice everything is created first in the mind, then in reality. Just because someone stumbles and loses their way, doesn’t mean they’re lost forever.” Never underestimate your ability to make someone else’s life better even if you never know it.” Everything you want is on the other side of fear” So dust off your sh*tkickers & let’s get started. Dear self, this is going to be your year. Rise up start fresh see the bright opportunity in each new day” The struggle you’re today is developing the strength you need for tomorrow” The darkest nights produce the brightest stars” If there’s no light at the end of the tunnel, march on down there and turn it on yourself.” Doubt kills more dreams than failure ever will.” Just because it’s hard doesn’t mean it’s impossible. A strong woman is one who is going to overcome all obstacles in her path and always keeping a smile on her face and making as if nothing happened” Inspirational Quotes & Sayings Rise up start fresh see the bright opportunity in each new day.” Ride out those chances while you still can.” Step out of your current reality and then take another step. Does this mean you shouldn’t do them? Absolutely not. Because most of the time, things that are worth doing are either massively inconvenient, exhausting or terrifying. Wish apon a shooting star listen to your dreams. Diamonds are formed under pressure but never forget they are not formed over night” ![]() 【Compatibility】- Designed for Amazon All-New Kindle Fire 7 Tablet (compatible with 12th generation, 2022 release), Please confirm your tablet model before purchasing, Whether it is used by kids or adults, it can perfectly protect your tablet.【Multi-layer protection】- Blended with soft shock-absorbing TPU skin and impact-resistant polycarbonate, The outer soft and inner hard structure can provide excellent protection performance, Unique internal grooves to assist with drop protection and heat dissipation, Integrated front cover screen protector prevents scratches without sacrificing sensitivity or visibility.Look at reviews – Reviews can be a great way to determine if a product is worth your money.Here are some tips for finding the best fire tablet 7 accessories: Things to Consider When Choosing fire tablet 7 accessories 【Perfect control】- The precise notch allows you to use all the functions of the tablet perfectly, including the charging port, headphone jack, volume button, start button, speaker, camera and so on.【Built-in Kickstand】- The built-in stand that can be easily popped up and collapsed allows you to comfortably access your favorite shows, movies and games at home or on the go, free your hands.【After-sales guarantee】- All DJ&RPPQ products include a 90-day worry-free refund and a 180-day return and exchange service, If you encounter any problems, please feel free to contact us, We will give you a satisfactory solution within 8 hours. Don't buy cheap – There are many online stores selling cheap stuff that looks like it should cost more than it does (especially when you see how much other retailers sell similar items).Look for descriptions that give you enough information about how things work and why you might want them in your life before you buy anything! Read through descriptions – Sometimes, when companies make things sound better, it can be hard to figure out what something does.If people have bought and liked it, it's probably worth buying too. ![]() See the announced dates below, along with a retrospective video for the tour that recounts some of John’s most celebrated compositions. Louis, Denver, Portland, OR, Nashville, Texas, Florida and many more. The tour will also hit Asia, and Australasia in 2019-20 and South America in 2020 before returning to Europe and the UK in late 2020 and North America again in 2021. The first round of North American gigs include stops at New York’s Madison Square Garden and Brooklyn’s Barclay’s Center, plus venues in Los Angeles, Chicago, Boston, St. The initial dates run through June 2019, with the North American and first batch of European dates included. ![]() I need to dedicate more time to raising my children.” After the tour finishes, I’m very much looking forward to closing off that chapter of my life by saying farewell to life on the road. I plan to bring the passion and creativity that has entertained my fans for decades to my final tour. “Performing live fuels me and I’m ecstatic and humbled to continue to play to audiences across the globe. “It’s time to come off the road so I can fully embrace the next important chapter of my life,” John says in a press release. The tour kicks off September 8 in Allentown, PA. Elton John has announced his massive “Farewell Yellow Brick Road” world tour, which will mark the legendary singer-songwriter’s retirement from touring over a three-year period of over 300 shows. ![]() If you have any doubts as to whether or not something is returnable, check with customer service. What If I Return Something To You That Is Not Yours? Please e-mail or call customer service if you need further assistance. Paperback Books with a retail price of $6.95 or less have Strippable Covers, regardless of product code (can be MM, TR, or PB.)Ĭalendars are strippable, but the cover with the barcode on it is required. To tell if an item is strippable, look for an inverted triangle with an (S) in it. Hachette Book Group Retail Sales & Marketingģ26 South Enterprise Blvd Lebanon, IN 46052 What Is Strippable? Returnable accounts can return any book for any length of time as long as the books are In Print and In Good Condition. How Long Can I Return For If I Am A Returnable Account? 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Indeed, the redemption of Bo is handled superbly, with the character displaying zero tropey, on-the-nose “girl power” we see too often in blockbusters cynically marketing shallow-but-strong female characters as progressive (Marvel does this rather a lot).īo’s dramatic personality shift is explained by her backstory, which sees her become a victim of her passive nature, spending years collecting dust on the shelf of an antique store, before growing sick of her self-imposed stagnation and taking life into her own hands.īo’s journey also provides a great metaphor for the parents who find themselves drifting aimlessly, lacking purpose after their kids grow up, before reshaping their identity into an independent spirit.įinally, Bo’s evolution shifts her from Woody’s cute girlfriend into something resembling a soulmate, with the two toys firmly addicted to adventure, choosing to spend the rest of their years enjoying a never-ending road trip. Find quality entertainment products to add to your Shopping. Barbie’s introduction and Bo’s gradual erasure perfectly mirror each other, but her quiet disappearance sparked a fantastic storytelling opportunity for the fourth film, an organic continuation of a tale that seemed firmly wrapped up after the bittersweet finale of Toy Story 3.Īmusingly enough, Toy Story 4 acknowledges Bo’s fragility while simultaneously dismissing it, Bo’s arm having snapped off during one of her many adventures, then casually taped back together. Shop for Fisher-Price Little People Toy Story Figures - Woody & Bo Peep (2 pc) at Pick n Save. ![]() When smoked, cocaine reaches the brain in 15 s. Write the melting point range of caffeine. It vaporizes at the temperature of a burning cigarette. Caffeine C8H10N4O - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Draw out the full structure of caffeine, showing all the bonds and lone pairs. The non-bonding electrons on each atom are present as lone pairs. Identify the location of all lone pairs in this compound: H3C CH3 N N N N. The space-filling model for caffeine is shown in Figure 3. Crack cocaine is more volatile than cocaine hydrochloride. 1.56 Below is the structure of caffeine, but its lone pairs are not shown. The name acetaminophen, which resembles 'aceto', 'amine', and 'phenol', which suggests that it looks like an acetoamide and phenol, which it does: 1) London Dispersion London dispersion is the weakest intermolecular force, and it is regarding an induced dipole. of caffeine: H O N C Complete a Lewis structure for caffeine in which all. Caffeine has 3 delocalised lone pairs of electrons on 3 nitrogens and only one N has electrons pair away from the aromatic r View the full answer. The Lewis structure helps us identify the bond pairs and the lone pairs. ![]() Although the Lewis theory does not determine the shapes of molecules, it is the first step in predicting shapes of molecules. The caffeine molecule contains a total of 25 bond(s) There are 15 non-H bond(s), 7 multiple bond(s), 2 double bond(s), 5 aromatic bond(s), 1 five-membered ring(s), 1 six-membered ring(s), 1 nine-membered ring(s), 1 urea (-thio) derivative(s), 1 imide(s) (-thio) and 1 Imidazole(s).\nonumber \]īecause it is soluble in water, cocaine hydrochloride is readily absorbed through the watery mucous membranes of the nose when it is snorted. Science Chemistry The structure of caffeine, present in coffee and many soft drinks, is shown here. Therefore, add lone pairs and multiple bonds to the structure below to give. Introduction To determine the shapes of molecules, we must become acquainted with the Lewis electron dot structure. ![]() How many lone pairs are in a caffeine molecule? The important thing to remember is that double bonds are comprised of 1 sigma bond and 1 pi bond and triple bonds are comprised of 1 sigma bond and 2 pi bonds. ![]() Every time you are asked to determine the number of pi or sigma bonds in a compound, you must draw its Lewis structure. Therefore, there are 8 lone pairs in caffeine. Oxygens with two bonds and a full octet will have two lone pairs, while nitrogens with three bonds and a full octet will have one lone pair. Suggested solution Thymine, a pyrimidine, has an alkene and lone pair. The elements of interest in caffeine for lone pairs are nitrogen and oxygen uncharged carbons will have no lone pairs. Me Me O N N Me N O HN N N H O Me thymine caffeine Purpose of the problem Revision. Read also : How does virtue ethics differ from deontology? How many lone pairs can you have? ![]() This permission is granted to anonymous and authenticated users when you use the Standard installation profile. This permission is required to access the search. This permission allows access to the “Advanced search” field-set. This permission let’s you access the “Search pages” configuration page. The Search module comes with three permissions: “Administer search”, “Use advanced search” and “Use search”. I mentioned in the last section that certain parts of the search page, i.e., “Advanced search” and the Users tab are only accessible if you have permission. So to search for content enter in a keyword into “Enter your keywords” and click search icon. This can be changed by adjusting permissions in Drupal. If you’re an anonymous user, by default you won’t see the “Advanced search” field-set and the Users tab. If you’re logged in as an administrator, you’ll see Content, Users and “Site search” (the one we created). To access the search page directly go to /search and you should see all the search pages as tabs. Once indexed you should see “100% of the site has been indexed.”. It can be ran manually by going to “admin/config/system/cron” and clicking on “Run cron”. If you see “0% of the site has been indexed.”, then make sure you index the site, by running cron. To check the index status, go to the “Search pages” page, the one we’re previously on and look at the “Indexing progress” section. If it hasn’t then nothing will appear in the search results. Once you’re back on the “Search pages” page, you can reorder how they’re displayed.Īnd, you can set the default page by clicking on the down arrow in the “Operations” column.īefore we can test the search page make sure the site content has been indexed. Then scroll to the bottom and click on “Add search page”.ĥ. Enter “Site search” in the Label field and add site to Path. From the “Search page type” select Content then click on “Add new page”.Ĥ. Scroll down to the “Search pages” section and from here you can manage the existing pages and create new ones.ģ. Go to Configuration, and click on “Search pages” from within the “Search and Metadata” section.Ģ. Select which content types you want generated and click on Generate. Just install the sub-module and then go to Configuration, “Generate content”. So to generate test content, I’ll use the “Devel generate” sub-module which ships with Devel. If you’re like me, you don’t like to spend too much time creating dummy content only to have it blown away. It’s useful to have real content indexed while building a search page. If you’re using the Minimal profile, then you’ll need to install the Search module manually. By using the Standard profile, it’ll automatically install and configure the core Search module. Just make sure you’ve installed Drupal using the Standard installation profile. In this tutorial, you’ll learn how to create a custom search page and how to modify the search results by overriding a template. If you want to index extra fields or remove ones from being indexed, you’ll still need Search API to do this. Second, you can only adjust the content ranking on these pages. First, it’ll have a prefix of “search/” in front but the full URL can be changed by creating a URL alias. However, there’re a few limitations to creating a search page. One of the big changes, for site builders, in Drupal 8 is the ability to create custom search pages. But the core Search module for Drupal 8 has become more powerful than in Drupal 7. If you need to create custom search pages in Drupal 7, more often than not, you use Search API or create a search page using Views. Long story short, something you thought would be as simple as enabling a module, ends up taking twice as long. At first a client will want something which users can search content, then they may want to modify the search results or even change the ranking of certain content. Building a search page isn’t as straight forward as you’d think. |
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